μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
نویسندگان
چکیده
The title compound, [Fe(4)(C(5)H(5)OS)(2)S(CO)(12)], was prepared by the direct reaction of Fe(3)(CO)(12) and 2-furyl-methane-thiol in tetra-hydro-furan. Desulfurization took place readily to form an Fe(4)S(3) cluster. The mol-ecule consists of two similar [(μ-2-C(4)H(3)O-CH(2)S)Fe(2)(CO)(6)] moieties joined to a spiro-type four-coordinate μ(4)-S atom such that this bridging sulfur is tetra-hedrally coordinated to the four Fe atoms. In each diiron subcluster core, the 2-furyl-methane-thiol-ate ligand bridges the two Fe atoms.
منابع مشابه
Bis{μ-[4-(1,3-benzothiazol-2-yl)phenyl]methanethiolato-κ4 S,S′:S,S′}bis[tricarbonyliron(I)](Fe—Fe)
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